Sounds like what happened with my faulty BA6592F. It worked for a few minutes before the video went completely out of sync and the blue progressively got weaker. The faulty chip would actually work correctly if I bypassed the amp on the Luminance or if I directly put the sync on the Luminance output, in which case, anything gray or white would show up black (a clear sign there's no luminance being output from the transistor at all). This would, however, make the picture much darker and more saturated, so you would need to put stronger resistors at the red and blue outputs after they're amplified.
I must also ask: where are you taking the RGB from? The video encoder's RGB inputs or outputs? Remember this: you must use clamped RGB for my circuit to work correctly.

